Nuclear wastes management is very serious problem. Although fission technology is well known and developed, generation IV fission reactors are to start operation in near future and nuclear safety level in new reactors is undoubtedly high, nuclear wastes problem has no satisfying solution that allow to stop considering influence of nuclear power plant on environment. The matter is worrying because, the fission reactors has been operating since years 50's of last century and nuclear wastes are accumulated and stored in temporary depositories. Using the word "temporary" is particularly unsuitable term, because i.e. in the USA, spent fuel and all radioactive wastes are stored through all reactor's life time. After removing spent fuel from the reactor it requires a storage with intensive cooling system due to existing of after-heat. Fuel rods after reload consists large amount of highly radioactive fission products. Majority of energy gained by fission is transferred to the coolant in the reactor core. But part of them is being released long time after the reaction occurs because of radiation and the fact that it is impossible to stop all reaction undergoing in the fuel at one moment. From the core, spent fuel is transported to surface storage with efficient cooling system. For this purpose water pools are appropriate. They are 12 m deep and keep spent fuel at temperature of around 40ºC. Pools are first but very long stage of wastes management. Spent fuel is required to be kept under water from several years to decades to reduce radioactivity and after-heat. Spent fuel can be in general treated in two ways. It can be transported to deep geological depository or to recycling facility. Second solution is expensive and not very popular worldwide. The issue was presented in point 2.4.2.2 of the thesis. Nevertheless fuel recycling is less harmful for the environment, rational in relation to resources management and compatible with sustainable development policy. According to [92] projections, amount of spent fuel in storage will be steadily increasing and will reach 450 000 tons of heavy metal (t HM) in 2020. Around of 120 000 tons will be reprocessed, the rest of 320 000 tons will be directed for storage. Today it is 320 000 t HM discharged globally. 95 000 t HM has been reprocessed and 225 000 t HM are stored. Global capacities for reprocessing are only at level of 5 000 t HM annually. There are several types of nuclear wastes. Its division is shown below [19], [21], [93] [94]
For the HLW and TRU storage, multibarrier system is proposed - EBS (the engineered barrier system). First step is wastes vitrification (that is embedded in the glass structure). It is hardly soluble and radioactive nuclides are well combined. According to researches vitrification give very strong and endure product resistant to mechanical stresses and water activity. Scientist said that they are able to keep radioactive nuclides combined even for 1000 years with minimal radioactivity leakage to the water or ground. Wastes are formed in a compact cylinder that can be placed in a sealed cooper or stainless steel container. As long as container is not broken, any nuclides can not get outside to the environment. Nevertheless corrosion is a problematic issue and eventual tectonic movements, that can not be predicted, especially that containers have to be stored for thousands years. Additionally container's endurance can turn out to be much worse that vitrification product. The container is surrounded by bentonite clay. It protects vessel from small rock's movements and set it in one place. Moreover the clay separate the container from water and it acts like a filter of nuclides. It binds radioactive particles with itself. Last important barrier is final geological repository meeting with very rigorous requirements. Rocks should effectively protect containers from water and mechanical damages. In caves, hydrochemical conditions are favourable and permanent what is their comparative advantage. [93] There are several options for a final geological depository of spent fuel. The most significant are [83]:
However, to date, none of final geological repository is in operation. Radioactive spent fuel is not the only nuclear waste. All solid, liquid and gas wastes, containing radioactive particles or contaminated by radioactive materials, are called nuclear waste. Hence all nuclear industry is a large source of threatening wastes. Moreover all nuclear power plant's elements after decommissioning are wastes as well as usable equipment in the power plant. [93] The amount of low level wastes after decommissioning is average 10 000 m3. [82] Major radioactivity in nuclear power plant is caused by activation process. Steel elements normally not radioactive, gain radioactivity due to long neutrons bombardment. [94] [7] [19],[21],[82],[83],[91],[92]